In geometry, tetrahedron packing is the problem of arranging identical regular tetrahedra throughout three-dimensional space so as to fill the maximum possible fraction of space.
Currently, the best lower bound achieved on the optimal packing fraction of regular tetrahedra is 85.63%.[1] It has been known for hundreds of years that the tetrahedron does not tile space, but an upper bound below 100% (namely ) has only recently been reported.[2]
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Aristotle claimed that tetrahedra could fill space completely.[3]
In 2006, Conway and Torquato showed that a packing fraction about 72% can be obtained by constructing a non-Bravais lattice packing of tetrahedra (with multiple particles with generally different orientations per repeating unit), and thus they showed that the best tetrahedron packing cannot be a lattice packing (with one particle per repeating unit such that each particle has a common orientation).[4] These packing constructions almost doubled the optimal Bravais-lattice-packing fraction 36.73% obtained by Hoylman.[5] In 2007 and 2010, Chaikin and coworkers experimentally showed that tetrahedron-like dice can randomly pack in a finite container up to a packing fraction between 75% and 76%.[6] In 2008, Chen made a significant improvement, proposing a structure with a packing fraction of 77.86%.[7][8] A further improvement was made in 2009 by Torquato and Jiao, who compressed Chen's structure using a computer algorithm to a packing fraction of 78.2021%.[9] Later these same authors obtained a denser random tetrahedron packing with a packing fraction of 82.26% using the same algorithm.[10]
In mid 2009 Haji-Akbari et al. showed, using MC simulations of initially random systems that at packing densities >50% an equilibrium fluid of hard tetrahedra spontaneously transforms to a dodecagonal quasicrystal, which can be compressed to 83.24%. For a periodic quasicrystal approximant with an 82-tetrahedron unit cell, they obtained a packing density as high as 85.03%.[11]
In late 2009, a new, much simpler family of packings with a packing fraction of 85.47% was discovered by Kallus, Elser, and Gravel.[12] These packings were also the basis of a slightly improved packing obtained by Torquato and Jiao at the end of 2009 with a packing fraction of 85.55%,[13] and then by Chen, Engel, and Glotzer in early 2010 with a packing fraction of 85.63%.[1]
Because the earliest lower bound known for packings of tetrahedra was less than that of spheres, it was suggested that the regular tetrahedra might be a counterexample to Ulam's conjecture that the optimal density for packing congruent spheres is smaller than that for any other convex body. However, the more recent results have shown that this is not the case.